How to create/disable/delete a zimbra account using PHP:
Login as Zimbra using su - zimbra
Create PHP file with Zimbra commands.
When you are executing Zimbra command using PHP, use
shell_exec('/opt/zimbra/bin/');
For example:
shell_exec('/opt/zimbra/bin/zmprov sp user@example.com ');
Lastly, add a cron job using crontab -e
*/1 * * * * php /var/www/phpfile.php